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李超

职称: 正高

直属机构: 物理与电子科学学院

学科:

10 访问

相关教师

个人资料

  • 部门: 物理与电子科学学院
  • 性别:
  • 专业技术职务: 青年研究员、博导
  • 毕业院校: 华东师范大学
  • 学位: 博士
  • 学历: 研究生
  • 联系电话: 13162308153
  • 电子邮箱: lchao@phy.ecnu.edu.cn
  • 办公地址: 闵行校区光学大楼B521
  • 通讯地址: 闵行校区光学大楼B521
  • 邮编: 200241
  • 传真:

教育经历

2013.9-2018.6,华东师范大学, 博士(指导老师:陈群&胡炳文)

2009.9-2013.6,华东理工大学, 本科

工作经历

2021.12-目前,华东师范大学,物理与电子科学学院,青年研究员(博士生导师)

2018.9-2021.11,华东师范大学,物理与电子科学学院,副研究员

个人简介

社会兼职

研究方向

主营业务

(1)电化学原位(In-situ)固体核磁共振、电子顺磁共振技术

(2)锂/钠离子电池高压正极材料结构及机理研究

(3)氧元素有关阴离子氧化还原活性材料的设计和机理研究

(4)高压正极材料/电解液界面分析


涉及业务

(1)核磁共振成像、顺磁共振成像

(2)高场核磁共振、高频顺磁共振

(3)同步辐射吸收谱技术(XAFS/sXAS)、磁性测量、微分电化学质谱(DEMS)和拉曼光谱


欢迎物理(凝聚态物理)、化学(电化学、物理化学、无机化学)、材料背景的学生报考硕士、博士。招生专业:无线电物理(博士为申请考核制。详细报考信息请查询华东师范大学研究生招生信息网。

开授课程

科研项目

(1)国家自然科学基金青年科学基金项目,21902049 ,氟氧磷酸盐正极材料的电化学反应机理——固体核磁共振、电子顺磁共振波谱的交叉研究,20201-202212月,30.6万,在研,主持

(2)上海市科委扬帆计划项目,19YF1413000,电子顺磁共振、固体核磁共振与顺磁性正极材料的充放电机理研究,20195-20224月,20万,在研,主持

(3)上海市教育委员会晨光计划,磁共振技术研究顺磁性正极材料的电化学反应机理 ,2021年1月-2023年12月,5万,在研,主持

学术成果

论文目录及引用:

http://orcid.org/0000-0002-0153-7825

https://publons.com/researcher/2217555/chao-li/


1.钠/锂离子电池正极材料研究

Chong Zhao, Hui LiuFushan Geng, Bingwen HuChao Li*Stable electronic structure related with Mn4+─O-• coupling determines the anomalous nonhysteretic behavior in Na2Mn3O7. Energy Storage Mater. 2022, 48, 290296.

Hui LiuChao Li*, Chong Zhao, Wei Tong, Bingwen Hu*. Coincident formation of trapped molecular O2 in oxygen-redox-active archetypical Li 3d oxide cathodes unveiled by EPR spectroscopy. Energy Storage Mater. 2022, 50, 5562.

Bei Hu, Qing Qiu, Chao Li*Ming Shen, Bingwen Hu, Wei Tong, Kunchan Wang, Qingping Zhou, Yanming Zhang, Zhiyan He, Teng Zhang, Changxin Chen. Tailoring Anionic Redox Activity in a P2-Type Sodium Layered Oxide Cathode via Cu Substitution. ACS Appl. Mater. Interfaces 2022, 14, 28738−28747.

- Chong Zhao, Chao Li*Hui LiuQing QiuFushan GengMing ShenWei TongJingxin LiBingwen Hu*Coexistence of (O2)n− and Trapped Molecular O2 as the Oxidized Species in P2-Type Sodium 3d Layered Oxide and Stable Interface Enabled by Highly Fluorinated Electrolyte. J. Am. Chem. Soc. 2021, 143, 18652−18664.

Bei Hu, Fushan Geng, Ming Shen, Chong Zhao, Qing Qiu, Yang Lin, Changxin Chen,Wen Wen, Shun Zheng, Xiaoshi Hu, Chao Li*, Bingwen Hu*. A multifunctional manipulation to stabilize oxygen redox and phase transition in 4.6 V high-voltage LiCoO2 with sXAS and EPR studies. J. Power Sources 2021, 516, 230661.

- Chong Zhao, Chao Li*Qi Yang, Qing Qiu, Wei Tong, Shun Zheng, Jingyuan Ma, Ming Shen, Bingwen Hu*. Anionic redox reaction in Na-deficient layered oxide cathodes: Role of Sn/Zr substituents and in-depth local structural transformation revealed by solid-state NMR. Energy Storage Mater. 2021, 39, 60–69.

- Hui Liu, Chong Zhao, Qing Qiu, Bei Hu, Fushan Geng, Jingxin Li, Wei Tong, Bingwen Hu, Chao Li*What Triggers the Voltage Hysteresis Variation beyond the First Cycle in Li-Rich 3d Layered Oxides with Reversible Cation Migration? J. Phys. Chem. Lett.2021, 12, 8740–8748.

- Qing Qiu, Chao Li*Hui Liu, Yuxin Liao, Chong Zhao, Fushan Geng,  Ming Shen, Jingxin Li, Wei Tong, Bingwen Hu*. NMR Evidence for the Multielectron Reaction Mechanism of Na3V2(PO4)3 Cathode and the Impact of Polyanion Site Substitution. J. Phys. Chem. C. 2021, 125, 15200−15209.

- Chong Zhao, Qi Yang, Fushan Feng, Chao Li*, Nian Zhang, Jingyuan Ma, Wei Tong, Bingwen Hu. Restraining Oxygen Loss and Boosting Reversible Oxygen Redox in a P2-Type Oxide Cathode by Trace Anion Substitution. ACS Appl. Mater. Interfaces 2021, 13, 360−369.

- Bei Hu, Fushan Geng, Chong Zhao, Bertrand Doumert, Julien Trébosc, Olivier Lafon, Chao Li*, Ming Shen*, Bingwen Hu. Deciphering the Origin of High Electrochemical Performance in a Novel Ti-substituted P2/O3 Biphasic Cathode for Sodium-Ion Batteries. ACS Appl. Mater. Interfaces 2020, 12, 41485–41494.

Chao Li*, Fushan Geng, Bei Hu, Bingwen Hu*. Anionic redox in Na-based layered oxide cathodes: a review with focus on mechanism studies. Mater. Today Energy 2020, 127, 100474.(综述)

Chao Li*, Chong Zhao, Bei Hu, Wei Tong, Ming Shen, Bingwen Hu*. Unraveling the Critical Role of Ti Substitution in P2NaxLiyMn1yOCathodes for Highly Reversible Oxygen Redox Chemistry. Chem. Mater. 2020, 32, 10541063.

Chao Li, Ming Shen, Bei Hu, Xiaobing Lou,Xi Zhang, Wei Tong, Bingwen Hu. High-Energy Nanostructured Na3V2(PO4)2O1.6F1.4 Cathode for Sodium-Ion Batteries and a New Insight into Its Redox Chemistry. J. Mater. Chem. A 2018, 6, 8340–8348.

Yuxing Liao#, Chao Li#, Xiaobing Lou, Xiaoshi Hu, Yanqun Ning, Fengyi Yuan, Bo Chen, Ming Shen,Bingwen Hu. Carbon-Coated Li3V2(PO4)3 Derived from Metal-Organic Framework as Cathode for Lithium-Ion Batteries with High Stability. Electrochimica Acta 2018, 271, 608-616.


2.原位固体核磁共振、电子顺磁共振

Chao Li, Ming Shen, Xiaobing Lou, Bingwen Hu.Unraveling the Redox Couples of VIII/VIV Mixed-Valent Na3V2(PO4)2O1.6F1.4Cathode by Parallel-Mode EPR and In Situ/Ex Situ NMR. J. Phys. Chem. C 2018, 122, 27224-27232.

Jianyin Wang, Mengchu Yang, Chong Zhao, Bei Hu, Xiaobing Lou, Fushan Geng, Wei Tong, Bingwen Hu, Chao Li*. Unveiling the benefits of potassium doping on the structural integrity of Li–Mn-rich layered oxides during prolonged cycling by dual-mode EPR spectroscopy. Phys. Chem. Chem. Phys. 2019, 21, 24017-24025.

Chao Li,  Ming Shen, Bingwen Hu*Solid-State NMR and EPR Methods for Metal Ion Battery ResearchActa Phys. -Chim. Sin. 2020, 36, 1902019.(综述)

- Fushan Geng, Qi Yang, Chao Li, Ming Shen, Qun Chen, Bingwen Hu. Mapping the Distribution and the Microstructural Dimensions of Metallic Lithium Deposits in an Anode-Free Battery by In Situ EPR Imaging. Chem. Mater. 2021, 33, 8223−8234.

- Fushan Geng, Qi Yang, Chao Li, Bei Hu, Chong Zhao, Ming Shen, Bingwen Hu. Operando EPR and EPR Imaging Study on a NaCrO2 Cathode: Electronic Property and Structural Degradation with Cr Dissolution. J. Phys. Chem. Lett. 2021, 12, 781−786.

- Bei Hu, Xiaobing Lou, Chao Li, Fushan Geng, Chong Zhao, Jianyin Wang, Ming Shen, Bingwen Hu. Reversible phase transition enabled by binary Ba and Ti-based surface modification for high voltage LiCoO2 cathode. J. Power Sources 2019, 438, 226954.



3.MOFs材料研究

Chao Li#, Qi Yang#, Ming Shen, Jingyuan Ma, Bingwen Hu. The electrochemical Na intercalation/extraction mechanism of ultrathin cobalt(II) terephthalate-based MOF nanosheets revealed by synchrotron X-ray absorption spectroscopy. Energy Storage Mater. 2018, 14, 82-89.

Chao Li, Xiaoshi Hu, Wei Tong, Wensheng Yan, Xiaobing Lou, Ming Shen, Bingwen Hu. Ultrathin Manganese-Based Metal−Organic Framework Nanosheets: Low-Cost and Energy-Dense Lithium Storage Anodes with the Coexistence of Metal and Ligand Redox Activities. ACS Appl. Mater. Interfaces 2017, 9, 29829−29838.

Chao Li, Xiaobing Lou, Ming Shen, Xiaoshi Hu, Wensheng Yan, Youming Zou, Wei Tong, Bingwen Hu. High-capacity cobalt-based coordination polymer nanorods and their redox chemistry triggered by delocalization of electron spins. Energy Storage Mater. 2017, 7, 195–202.

Chao Li, Xiaoshi Hu, Xiaobing Lou, Qun Chen, Bingwen Hu. Bimetallic coordination polymer as a promising anode material for lithium-ion batteries.Chem. Commun. 2016, 52, 2035—2038.

Chao Li, Xiaoshi Hu, Xiaobing Lou, Lijuan Zhang,Yong Wang, Jean-Paul Amoureux, Ming Shen, Qun Chen, Bingwen Hu. The organic-moiety-dominated Li+ intercalation/deintercalation mechanism of a cobalt-based metal–organic framework. J. Mater. Chem. A 2016, 4, 16245–16251.

Chao Li, Xiaobing Lou, Ming Shen, Xiaoshi Hu, Zhi Guo, Yong Wang, Bingwen Hu, Qun Chen. High Anodic Performance of Co 1,3,5-Benzenetricarboxylate Coordination Polymers for Li-Ion Battery. ACS Appl. Mater. Interfaces 2016, 8, 15352−15360.

Chao Li, Xiaoshi Hu, Bingwen Hu. Cobalt(II) dicarboxylate-based metal-organic framework for long-cycling and high-rate potassium-ion battery anode. Electrochimica Acta 2017, 253, 439–444.

Chao Li, Xiaobing Lou, Qi Yang, Youming Zou, Bingwen Hu. Remarkable improvement in the lithium storage property of Co2(OH)2BDC MOF by covalent stitching to graphene and the redox chemistry boosted by delocalized electron spins. Chem. Eng. J. 2017, 326, 1000–1008.

Chao Li, Taiqiang Chen, Weijing Xu, Xiaobing Lou, Likun Pan, Qun Chen, Bingwen Hu. Mesoporous nanostructured Co3O4 derived from MOF template: a high-performance anode material for lithium-ion batteries. J. Mater. Chem. A 2015, 3, 5585–5591.






荣誉及奖励