About
- Department: School of Physics and Electronic Science
- Gender: male
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- Graduate School:
- Degree:
- Academic Credentials:
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- Email: bwhu@phy.ecnu.edu.cn
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- Address: Optics Building B519 (Dongchuan Road 500)
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Education
BAC+MASTER, Fudan University, BAC+MASTER (Ping Zhou)
PhD, University of Lille I, Phd (JP Amoureux), National Centre for Ultra-High Field Nuclear Magnetic Resonance (Lille)
WorkExperience
2009.12-2014.7, Associate Professor
2014.8-2021.12, Professor
2018.7-present, Vice President of the School
2020.12-present, Deputy Director of Shanghai Key Laboratory of Magnetic Resonance
Resume
Hu Bingwen, is the senior editor of the Journal of Physical Chemistry Letters (July 2023- now), holds a position of Zijiang Professor in East China Normal University. He is currently the deputy director of the Shanghai Key Laboratory of Magnetic Resonance and the deputy dean of the School of Physics and Electronic Science.
He studied at Fudan University for bachelor's and master's degrees, and got PhD degree at the French Ultra high-Field Nuclear Magnetic Resonance Research Center at the University of Lille I, France, where he was engaged in the development of new NMR methods. After return to China, he focusses in the development of new technologies for NMR and EPR and their application in lithium-ion and sodium-ion battery systems. He has published more than 200 articles. He was supported by the Excellent Youth Fund of the National Natural Science Foundation of China in 2015. He was a recipient of YuanZhi Outstanding Youth EPR award in 2022. He gave plenary talks at the 2014 and 2021 National Magnetic Resonance Conferences, and participated in the following important conferences and gave invited talks: 2022 Fall Meeting of the Chinese Physical Society (F Branch: Nano and Mesoscopic Physics ), 2023 33rd Congress of the Chinese Chemical Society (44th Sub-session: Nanodevices, Nano Characterization and Detection Technology), 2024 Experimental Nuclear Magnetic Resonance Conference (ENC).
* Zijiang Professor in East China Normal University * Deputy director of the Shanghai Key Laboratory of Magnetic Resonance * Deputy dean of the School of Physics and Electronic Science * Recipient of YuanZhi Outstanding Youth EPR award * chairman of the Physics Academic Degree Evaluation Committee
* member of the 12th Academic Degree Evaluation Committee of ECNU * Senior editor of the Journal of Physical Chemistry Letters
Research Fields
(1) Magnetic resonance imaging (MRI) technology and electron paramagnetic resonance (EPR) imaging technology to study the materials of lithium-ion batteries (including solid electrolytes)
(2) In situ/ex situ solid NMR, in situ/ex situ EPR for the materials of lithium-ion batteries (including solid electrolytes)
(3) Development of new methods for solid-state NMR and new methods for EPR
(4) First-principles calculation of solid-state NMR and EPR ===================
Solid-state NMR capabilities:
(1) In situ technology (2) pulse development capabilities, such as IR-pj-MATPASS, DQ-HMQC;
(3) Extensive nuclear detection capabilities, such as 17O, 59Co, 51V and other special nuclei;
EPR capabilities:
(1) In situ technology and in situ imaging (2) Special-species detection capabilities, such as molecular oxygen O2
(3) the analytical ability, combined with condensed matter physics
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Dissertation： | Number | Title | Author | Type | Date | | 1 | Toward an Understanding of the Mechanism of Lithium Plating and Stripping via In Situ ESR Imaging | Geng Fushan | Postdoctoral | 2023/6/1 | | 2 | Magnetic Resonance Study on NaxA1-yMnyO2 (A = Mg, Zn) cathode materials based on oxygen valence variation | Chen Chen | Master | 2023/5/15 | | 3 | NMR Characterization and Ion Loss Studies of Cathode Materials for Sodium Ion Batteries | Liao Yuxin | doctor | 2023/5/10 | | 4 | Solid-state NMR study of high-voltage LiCoO2 and its doped product | Gu Suyu | Master | 2023/4/20 | | 5 | Magnetic Resonance Study of Li, Mn-Based Layered Oxide Cathode Materials Based on Oxygen Anion Redox | Liu Hui | doctor | 2023/3/22 | | 6 | Anionic Redox Mechanism Study of Sodium-ion Layered Oxide Cathode Materials | Zhao Chong | doctor | 2022/3/7 | | 7 | Research on reactive oxygen species of the Lithium-air battery by Electron Paramagnetic Resonance | Lin Yang | Master | 2022/3/1 | | 8 | Magnetic Resonance Study on the Charge/Discharge Mechanism of Cathode Materials for Sodium Ion Batteries | Qiu Qing | Master | 2022/3/1 | | 9 | MAGNETIC RESONANCE IMAGING STUDY OF GRANULAR PACKING PROBLEMS | Xia Chengjie | Postdoctoral | 2021/11/30 | | 10 | Research on Visualization of the Sedimentation Process of Polydopamine Nanoparticles | Wang Shaoyan | Master | 2021/4/12 | | 11 | Adjusting the distribution of gold nanoparticles in core-shell structure and the application in photoluminescence | Zhang wei | Master | 2021/4/10 | | 12 | The Study of Battery Materials via Nuclear Magnetic Resonance and Electron Paramagnetic Resonance | Geng Fushan | doctor | 2021/4/10 | | 13 | Modification and Redox Chemistry Mechanism of Layered Oxide Cathode Materials for Lithium/Sodium Ion Batteries | Hu Bei | doctor | 2021/3/10 | | 14 | Synthesis and Mechanism Studies of Layered Oxide Cathode Materials for Lithium/Sodium-Ion Batteries | Wang Jianyin | Master | 2020/5/1 | | 15 | Studies on Magnetic Resonance Imaging Reconstruction and Computer-aided Diagnosis based on Artificial Intelligence | Song Yang | doctor | 2019/5/10 | | 16 | Synthesis and Properties of High-Performance Layered Lithium-Rich Cathode Materials for Lithium Ion Batteries | Yang Mengchu | Master | 2019/5/8 | | 17 | Design, Synthesis and Modification of new-type Metal-Organic Frameworks (MOFs) as Cathodes or Anodes Materials for Lithium Ion Batteries | Lou Xiaobing | doctor | 2019/5/1 | | 18 | The Synthesis of Nanoporous Carbon Material and Applications in Lithium Oxygen Batteries | Ge Qiong | Master | 2019/4/1 | | 19 | Research on Cathode and Anode Materials of Lithium-Ion Batteries Based on Metal-Organic Frameworks | Wang Peng | Master | 2019/3/21 | | 20 | The Application of Cobalt Based Metal-Organic Framework Anodes in Lithium/Sodium Ion Batteries | Ning Yanqun | Master | 2018/6/6 | | 21 | The Application of Metal-Organic Frame Materials and Its Derived Phosphate in Lithium-ion Batteries | Liao Yuxing | Master | 2018/5/20 | | 22 | New Solib-state Nuclear Magnetic Resonance methods and their applications in battery materials | Shen Ming | Postdoctoral | 2018/4/1 | | 23 | The Redox Chemistry Studies of Metal-Organic Framework Anodes and Fluorophosphate Cathode by the Combination of NMR, EPR, and Synchrotron Radiation Techniques | Li Chao | Doctor* | 2018/5/1 | | 24 | Design, Synthesis and Electrochemical Properties of Metal-Organic Framework and its Derived Transition-Metal Oxide as Anode Materials for Lithium Ion Batteries | Hu Xiaoshi | Doctor* | 2018/5/1 | | 25 | Application of Metal Organic Framework Materials Based on 1,4-benzenedicarboxylic Acid Ligands in Lithium-ion Batteries | Hu Huiping | Master | 2017/5/31 | | 26 | The Application of Bimetallic Organic Framework for Lithium-ion Batteries | Li Tian | Master | 2017/4/10 | | 27 | Solid-state NMR for 15N-15N correlations and PEO/urea/alkali salts ternary solid polymer electrolytes | Yan Xiaojing | Master | 2016/6/28 | | 28 | New solid-state NMR methods and MOF anode materials | Peng Bo | Master | 2016/6/22 | | 29 | New solid-state NMR methods for homo-/hetero-nuclear correlations and spin=1 nucleus | Shen Ming | Doctor* | 2015/3/1 | | 30 | New pulse sequences for heteronuclear experiments and covariance for homonuclear experiments in SS-NMR | Li Yixuan | Doctor* | 2015/3/1 | | 31 | Preparation、characterization 、catalytic study of microporous palladium-loading MOFs as heterogeneous catalysts and study of covariance NMR spectroscopy | Qian Yi | Master | 2015/4/1 | | 32 | Solid-State NMR studies for poly(ethyl oxide)/LiAsF6 cyrstalline polymer electrolytes in solid lithium batteries | Liu Qinghua | Doctor* | 2014/3/1 | | 33 | Application of the NMR techniques in structural analysis of polysaccharides | Wang Linqiang | Master | 2013/4/1 | | 34 | Phase structures and segmental dynamics of poly(Ethylene Oxide)/LiCF3SO3 complexes as studied by solid-state high-resolution 13C nuclear magnetic resonance | Wei Ling | Doctor* | 2013/5/1 | | 35 | Design of heterogenous palladium catalyst on basis of solid-state NMR structural characterization | Zhang Siyong | Doctor* | 2013/4/1 |
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| *: Co-instruction with Prof. Chen Qun |
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Scientific
2022: National Foundation /NSFC - General Project
2018: National Foundation /NSFC - General Project
2015: NSFC-Outstanding Youth Fund Project
2013: National Foundation /NSFC - General Project
2011: National Foundation /NSFC - Youth Project
Academic Achievements
Publications: http://www.researcherid.com/rid/G-8930-2011 https://www.researchgate.net/profile/Bingwen_Hu/publications
Typical Papers：（Underlined papers are selected papers）
（1）EPR-NMR # EPR for metal-ion batteries (including in-situ EPR and in-situ EPR imaging) * Jiang, Y.; Lu, G.; Kang, S.; Geng, F.; Hu, B., All-Solid-State Batteries with Pre-plated Ultrathin Lithium Metal Enabled by No Pressure Holding and Characterized by In Situ Electron Paramagnetic Resonance Imaging. The Journal of Physical Chemistry Letters 2023, 14 (20), 4682-4687.
* Feng, H.; Yang, Q.; Li, C.; Lin, Y.; Liu, H.; Zhang, N.; Hu, B., Completely Eradicating Singlet Oxygen in Li–O2 Battery via Cobalt(II)-Porphyrin Complex-Catalyzed LiOH Chemistry. The Journal of Physical Chemistry Letters 2023, 14 (4), 846-853. * H. Liu, C. Li, C. Zhao, W. Tong, B. Hu, Coincident formation of trapped molecular O2 in oxygen-redox-active archetypical Li 3d oxide cathodes unveiled by EPR spectroscopy, Energy Storage Materials 50 (2022) 55-62. * B. Hu, F. Geng, M. Shen, B. Hu, The study of electrochemical cycle for LiCoO2 by dual-mode EPR, Magnetic Resonance Letters (2023) https://doi.org/10.1016/j.mrl.2022.04.002. * C. Zhao, C. Li, H. Liu, Q. Qiu, F. Geng, M. Shen, W. Tong, J. Li, B. Hu, Coexistence of (O2)n− and Trapped Molecular O2 as the Oxidized Species in P2-Type Sodium 3d Layered Oxide and Stable Interface Enabled by Highly Fluorinated Electrolyte, Journal of the American Chemical Society 143(44) (2021) 18652-18664. * F. Geng, Q. Yang, C. Li, M. Shen, Q. Chen, B. Hu, Mapping the Distribution and the Microstructural Dimensions of Metallic Lithium Deposits in an Anode-Free Battery by In Situ EPR Imaging, Chemistry of Materials 33(21) (2021) 8223-8234. * Y. Lin, Q. Yang, F. Geng, H. Feng, M. Chen, B. Hu, Suppressing Singlet Oxygen Formation during the Charge Process of Li-O2 Batteries with a Co3O4 Solid Catalyst Revealed by Operando Electron Paramagnetic Resonance, The Journal of Physical Chemistry Letters 12(42) (2021) 10346-10352. * B. Hu, F. Geng, M. Shen, C. Zhao, Q. Qiu, Y. Lin, C. Chen, W. Wen, S. Zheng, X. Hu, C. Li, B. Hu, A multifunctional manipulation to stabilize oxygen redox and phase transition in 4.6 V high-voltage LiCoO2 with sXAS and EPR studies, Journal of Power Sources 516 (2021) 230661. * F. Geng, Q. Yang, C. Li, B. Hu, C. Zhao, M. Shen, B. Hu, Operando EPR and EPR Imaging Study on a NaCrO2 Cathode: Electronic Property and Structural Degradation with Cr Dissolution, The Journal of Physical Chemistry Letters 12(2) (2021) 781-786. * Y. Liao, C. Li, X. Lou, X. Hu, Y. Ning, F. Yuan, B. Chen, M. Shen, B. Hu, Carbon-coated Li3V2(PO4)3 derived from metal-organic framework as cathode for lithium-ion batteries with high stability, Electrochimica Acta 271 (2018) 608-616. * C. Li, X. Lou, Q. Yang, Y. Zou, B. Hu, Remarkable improvement in the lithium storage property of Co2(OH)2BDC MOF by covalent stitching to graphene and the redox chemistry boosted by delocalized electron spins, Chemical Engineering Journal 326 (2017) 1000-1008. * C. Li, X. Lou, M. Shen, X. Hu, W. Yan, Y. Zou, W. Tong, B. Hu, High-capacity cobalt-based coordination polymer nanorods and their redox chemistry triggered by delocalization of electron spins, Energy Storage Materials 7 (2017) 195-202.
# NMR for metal-ion batteries (including in-situ NMR) * Lu, G.; Geng, F.; Guo, N.; Yao, S.; Shen, M.; Hu, B., Probing the degradation of LiCoO2 in batteries subjected to high-voltage cycling with 17O solid-state NMR spectroscopy. Chemical Communications 2023. * Liao, Y.; Feng, H.; Yang, Q.; Shen, M.; Jiang, Y.; Li, C.; Zhao, C.; Geng, F.; Hu, B., Oxygen Redox Activation at Initial Cycle to Improve Cycling Stability for the Na0.83Li0.12Ni0.22Mn0.66O2 System. ACS Applied Materials & Interfaces 2023, 15 (8), 10709-10717. * G. Lu, F. Geng, S. Gu, C. Li, M. Shen, B. Hu, Distinguishing the Effects of the Space-Charge Layer and Interfacial Side Reactions on Li10GeP2S12-Based All-Solid-State Batteries with Stoichiometric-Controlled LiCoO2, ACS Applied Materials & Interfaces (2022).
* C. Zhao, C. Li, Q. Yang, Q. Qiu, W. Tong, S. Zheng, J. Ma, M. Shen, B. Hu, Anionic redox reaction in Na-deficient layered oxide cathodes: Role of Sn/Zr substituents and in-depth local structural transformation revealed by solid-state NMR, Energy Storage Materials 39 (2021) 60-69. * Q. Qiu, C. Li, H. Liu, Y. Liao, C. Zhao, F. Geng, M. Shen, J. Li, W. Tong, B. Hu, NMR Evidence for the Multielectron Reaction Mechanism of Na3V2(PO4)3 Cathode and the Impact of Polyanion Site Substitution, J. Phys. Chem. C 125(28) (2021) 15200-15209. * Y. Liao, C. Li, F. Geng, M. Shen, B. Hu, Na3V2(PO4)3 Revisited: A High-Resolution Solid-State NMR Study, The Journal of Physical Chemistry C 125(43) (2021) 24060-24066. * B. Hu, X. Lou, C. Li, F. Geng, C. Zhao, J. Wang, M. Shen, B. Hu, Reversible phase transition enabled by binary Ba and Ti-based surface modification for high voltage LiCoO2 cathode, Journal of Power Sources 438 (2019) 226954. * F. Geng, M. Shen, B. Hu, Y. Liu, L. Zeng, B. Hu, Monitoring the evolution of local oxygen environments during LiCoO2 charging via ex situ 17O NMR, Chemical Communications 55(52) (2019) 7550-7553.
# EPR & NMR for metal-ion batteries * C. Li, C. Zhao, B. Hu, W. Tong, M. Shen, B. Hu, Unraveling the Critical Role of Ti Substitution in P2-NaxLiyMn1–yO2 Cathodes for Highly Reversible Oxygen Redox Chemistry, Chemistry of Materials 32(3) (2020) 1054-1063.
* F. Geng, B. Hu, C. Li, C. Zhao, O. Lafon, J. Trébosc, J.-P. Amoureux, M. Shen, B. Hu, Anionic redox reactions and structural degradation in a cation-disordered rock-salt Li1.2Ti0.4Mn0.4O2 cathode material revealed by solid-state NMR and EPR, Journal of Materials Chemistry A 8(32) (2020) 16515-16526. * C. Li, M. Shen, X. Lou, B. Hu, Unraveling the Redox Couples of VIII/VIV Mixed-Valent Na3V2(PO4)2O1.6F1.4 Cathode by Parallel-Mode EPR and In Situ/Ex Situ NMR, The Journal of Physical Chemistry C 122(48) (2018) 27224-27232.
（2）Solid-state NMR：
• Broad-band homo-nuclear correlations assisted by (1)H irradiation for bio-molecules in very high magnetic field at fast and ultra-fast MAS frequencies； • Broadband finite-pulse radio-frequency-driven recoupling (fp-RFDR) with (XY8)4(1) super-cycling for homo-nuclear correlations in very high magnetic fields at fast and ultra-fast MAS frequencies； • Very-Long-Distance Correlations in Proteins Revealed by Solid-State NMR Spectroscopy； • Composite pulses in directly and indirectly detected 14N MAS overtone spectroscopy • Reduction of the 13 C cross-polarization experimental time for pharmaceutical samples with long T1 by ball milling in solid-state NMR；
（3）NMR for polymer elctrolytes：
• Phase Structure and Helical Jump Motion of Poly(ethylene oxide)/LiCF3SO3 Crystalline Complex: A High-Resolution Solid-State C-13 NMR Approach； • Polymer chain diffusion and Li+ hopping of poly(ethylene oxide)/LiAsF6 crystalline polymer electrolytes as studied by solid state NMR and ac impedance； • PEO-urea-LiTFSI ternary complex as solid polymer electrolytes；
（4）DFT：
• Optimizing the U_eff value for DFT+U calculation of paramagnetic solid-state NMR shifts by double Fermi-contact-shift verification
（5）Review * B.-W. Hu, C. Li, F.-S. Geng, M. Shen, Magnetic Resonance in Metal-Ion Batteries: From NMR (Nuclear Magnetic Resonance) to EPR (Electron Paramagnetic Resonance), Journal of Electrochemistry 28(2) (2022) 2108421. * F. Geng, B. Peng, Y. Yao, Q. Chen, B. Hu, Chapter Six - Solid-state NMR studies on crystalline solid polymer electrolytes and important cathode materials for lithium-ion batteries, in: G.A. Webb (Ed.), Annual Reports on NMR Spectroscopy, Academic Press, 2020, pp. 265-308.
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