张利东

安徽师范大学 本科硕士

韩国釜山大学 博士

工作经历:

2016年9月-  今：华东师范大学化学系紫江青年学者，教授，博导。

2013年8月-2016年8月:  纽约大学阿布达比分校博士后研究员.

2009年3月-2013年3月: 韩国釜山国立大学高分子专业研究员助理.

2008年8月-2009年3月: 韩国釜山国立大学高分子专业专职研究员.

课题组成员

博士生

Advanced Materials,Journal of Materials Chemistry A/B/C, ACS Applied Materials and Interfaces, Langmuir, Chemical Communications 等多种杂志审稿人。

欢迎投稿：

本课题组主要专注于智能型高分子水凝胶新结构，新理论，新功能及新应用研究，以智能高分子的结构设计与化学合成为起点，通过深入研究结构与性能的关系，实现刺激响应性能与高分子结构的高度匹配，并通过对材料的特殊功能化，进一步拓展其应用潜质。多项创新性研究成果已发表在Nat. Commun., Adv. Mater.,Angew. Chem. Int. Ed., Adv. Funct. Mater., Chem. Commun., Macromol. Biosci., J. Control. Release. Polym. Chem.,等国际知名杂志发表。研究成果的主要创新体现在：首次合成和制备了基于琼脂糖的新型高分子低温湿气响应薄膜，是目前报道的最为敏感的低温水蒸气响应材料之一；对薄膜在湿气能量转化方面做了深入的研究，建立了新的能量转化机理模型，从宏观和微观两个方面阐明了高效湿气能量转化与材料结构性能的关系，为后续相关材料的发展提供了重要的理论依据；发展了化学“一步法”转化水凝胶薄膜到水凝胶管的新型理论和方法，实现了高性能水凝胶管的批量研制，成果受到了国家基金委，RSC，Nature Middle East、Gulf News Education等国内外多家媒体报道及高度评价。

具体研究领域：

高性能水凝胶微流管开发及应用研究 （微流控，可控催化，仿生器官）

电化学诱导水凝胶功能化 （结构调控，粘附调控，传感应用）

刺激响应型高分子凝胶制备及应用性能研究 （柔性机器人，仿生传感）

高强度弹性水凝胶制备及应用性能研究 （柔性传感，仿生皮肤）

生物医用高分子凝胶合成与应用研究 （仿生皮肤，伤口敷料，药物传递，生物探针）

本科菁英班《高分子化学A》

科研项目：

1）国家自然科学面上基金（项目批准号：52373263）电化学驱动离子定向迁移构建水凝胶表面三维有序结构机制研究 (2024年1月-2027年12月)

2）国家自然科学面上基金（项目批准号：51873064）一步法构筑复杂多支水凝胶微流管(2019年1月-2022年12月)

3）国家自然科学青年基金（项目批准号：51603068）琼脂糖薄膜的化学改性及湿气驱动的能量转化机理研究(2017年-2020年)。

4）紫江青年学者启动基金(2016年-2021年)。

5）上海自然科学基金（项目批准号：17ZR1440600) 柔性智能双层膜的仿生性能机理研究(2017年1月-2019年12月)。

6）上海自然科学基金（项目批准号：20ZR1418200) 电化学诱导凝胶表面图案化交联机制研究(2020年7月-2023年6月)。

7）重庆自然科学基金（项目批准号：cstc2021jcyj-msxmX0397) 光调控金属纳米粒子的选择性配位诱导水凝胶可逆变色机理研究 (2021年10月-2024年9月)。

企业委托项目：

1）抗冻杀菌水凝胶合成技术开发,2023年5月至2027年5月。

课题组主持国家自然科学基金3项 (面上2项，青年1项)，主持上海市自然科学基金2项 (面上1项，探索1项)，主持重庆自然科学基金面上1项,主持华东师范大学人才项目1项，发表科研论文60余篇包括Adv. Mater. (2篇), Mater. Horiz. (1篇), Nature Commun (1篇), Angew. Chem. In. Ed. (1篇), Adv. Funct. Mater. (1篇). Cell Rep. Phys. Sci (1篇). 影响因子>10的论文25篇。

1)  通过化学合成具有微孔道仿生结构的复合高分子薄膜, 模拟生物结构衍生规律，实现了对高分子柔性智能双层膜仿生行为的操控,在外场刺激下，能够保持数小时连续可逆的响应，有效解决了目前智能材料响应周期短的弊端。研究结果发表在Nature Commun, Cell Rep. Phys. Sci., Angew. Chem. In. Ed., Adv. Mater., Adv. Funct. Mater., J. Phys. Chem. Lett., J. Mater. Chem. A., Chem. Commun.等杂志上, 其中发表在Adv. Mater. 2017, 29, 1702231（被Wiley评为2017年度 10大热点文章）。

2)  提出化学“一步法”转化高分子薄膜到复杂多尺度中空结构新理论，该方法具有原始创新性及实用性，研究工作发表在Mater. Horiz.，Chem. Comm., ACS Appl. Mater. Interfaces 等杂志上，被英国皇家学会，选为2019年度最受欢迎的科研成果之一。

代表性论文列表：

2023年

52. Ziyue Yang and Lidong Zhang*, Photoresponsive Non-Cross-Linking Film Actuator that Bends Away from a Light Source.Macromolecules. In press, Cite this: https://doi.org/10.1021/acs.macromol.3c01263

51. Xiaxin Qiu, Shumin Liang and Lidong Zhang*, Electrochemistry-triggered microscopic wrinkle patterns that improve sensitivity of hydrogel sensors. ACS Materials Letter, 2023, Minor Revision.

50. Danqing Zhou, Jiahui Yu,* Qiuhua Zhao* and Lidong Zhang*. In situ molecular permeation of liquid cationic polymers into solid anionic polymer films enabling self-adaptive adhesion of hydrogel biosensors. Mater. Horiz. 2023, 10, 3622.

49. Xiaoyong Zhang*, Meiyue Jin, Liping Ding, Jinmei He, Yongping Bai, Lidong Zhang,* Selective in situ dynamic motion stay and recover under single NIR light in soft actuator by triggered Shape-Memory and phase transition of hydrogel. Chemical Engineering Journal 468 (2023) 143734.

48. B. Feng, Y. Zhang, N. Zen, Y. Huang, H. Su, Y. Sun, Lidong Zhang, W. Huang,* A mechanically robust and highly stretchable cross-linked dual-ionic conductive elastomer, Chemical Engineering Journal., 2023, doi.org/10.1016/j.cej.2023.145497.

47. Wenjin Wu, Han Yang, Jiakang Liu, Yiqian Luo, Guanhuan Mo, Zhigao Hu, Lidong Zhang,* and Kun Huang*. Thermally Reversible Cross-Linking of Recyclable Polyamide Materials Based on Schiff Base and Diels–Alder Reactions. Macromol. Rapid Commun. 2023, 2300252.

2022年

46. Xiaxin Qiu, Xiaowen Huang, Lidong Zhang*, Electrochemical Bonding of Hydrogels at Rigid Surfaces, Small Methods, 2022, Accept, In press.

45. Shumin Liang, Wei Huang and Lidong Zhang*, Fluorescent Mechanism and Optical Switching of Fluorophore-Free Organogel, Macromol. Rapid Commun. 2022, Accept, In press.

44. Mengda Xu, Xiaxin Qiu, Shumin Liang, Wei Huang and Lidong Zhang*, Phase-Transition-Triggered Optical Switching for Multistage Information Encryption/Decryption, Adv. Opt. Mater. 2022, Accept, In press.

43. Mengda Xu, Yan Miao, Xiaxin Qiu, Xiaodong Song, Qiuhua Zhao, Jiahui Yu,* and Lidong Zhang*,Swelling-Induced Information Camouflage and Optical Decryption on a Transparent Recoverable Hydrogel Surface,ACS Appl. Mater. Interfaces 2022, 14, 3591−3600.

42. Ziyue Yang, Wei Huang, and Lidong Zhang*, Multiple Responsiveness of Polymer Actuators, Macromol. Rapid Commun. 2022, 2200539.

41. Xiaowen Huang, Jimin Fu, Huiyan Tan, Yan Miu, Mengda Xu, Qiuhua Zhao, Yujie Xie, Shengtong Sun, Haimin Yao & Lidong Zhang,* Molecular movements of trehalose inside a single network enabling a rapidly-recoverable tough hydrogel, International Journal of Smart and Nano Materials, doi.org/10.1080/19475411.2022.2116735.

41. Xiaodong Song, Xiaxin Qiu, Xiaowen Huang, Mengda Xu, and Lidong Zhang*, Light-Driven Awn-Footed Soft Robots, Macromol. Mater. Eng. 2022, 307, 2101003.

39. Junting He and Lidong Zhang *, Chemical adhesion of a hydrogel on an elastomer surface enabling directionally-bendable actuators†, J. Mater. Chem. C, 2022,10,2938.

38. Xiaoyong Zhang,* Gui Zhang, Xinhua Huang, Jinmei He, Yongping Bai, and Lidong Zhang*，Antifreezing and Nondrying Sensors of Ionic Hydrogels with a Double-Layer Structure for Highly Sensitive Motion Monitoring，ACS Appl. Mater. Interfaces 2022, 14, 30256−30267.

2021年

37. Photogated Coordination Switching of Silver Nanoparticles for Reversible Coloration/Discoloration of Hydrogel.Fushun Wang, Anyang Cui, Zhigao Hu,* Lidong Zhang*, 2021, Advanced Optical Materials. Accept.

36. Physiologically-Regulated Adhesion of Hydrogels for Wound Dressing. Mengda Xu, Yan Miao, Jiahui Yu,*, Lidong Zhang,* Adv. Mater. Interfaces, 2021, Accepted.

35.Magnetocaloric Actuation of Soft Polymer Robots.Xiaowen Huang, Jiang Wei, Hai Wei, and Lidong Zhang*, Journal of Materials Chemistry C, 2021, Accepted.

34.Electrochemistry-Induced Improvements of Mechanical Strength, Self-Healing, and Interfacial Adhesion of Hydrogels. Yan Miao, Mengda Xu, and Lidong Zhang*. Adv. Mater. 2021, 2102308.

33. Conductive cold-resistant and elastic hydrogel: A potential bionic skin for human-machine interaction control over artificial limbs.Yan Miao, Mengda Xu, Jiahui Yu,* Lidong Zhang, * Sensors and Actuators: B. Chemical.  2021, 327, 128916.

32. Waxy rice amylopectin towards stretchable elastic conductive hydrogel for human motion detection. Xiao-dong Song, Xia-xin Qiu, Xiaowen Huang, Ya-qing Tu, Qiu-hua Zhao^* Ruyi Sun^* and Lidong Zhang,* 2021, New J. Chem., 45, 4210.

31.Magnetic Actuation of Hollow Swarming Spheres for Dynamic Catalysis. Shumin Liang, Yan Miao, Xiaoyan Zhu, Jiang Wei, Qing-Feng Zhan, Xinhua Huang, Lidong Zhang * . ACS Appl. Mater. Interfaces, 2021, https://dx.doi.org/10.1021/acsami.0c21021.

30.Qiwen Yan, Lina Mao, Bang Feng, Lidong Zhang, Yiqian Wu, and Wei Huang. Reversible Patterning Cross-Linked, Humidity-Responsive Polymer Films with Programmatically and Accurately Controlled Deformation ACS Appl. Mater. Interfaces. 2021, 13, 7608-7616.

2020年

 29.Quantitative Insights into the Post-Crosslinking Effects on Physical-Performance Improvement and Surface-Cracking Healing of Hydrogel,Xiaxin Qiu, Yan Miao, Lidong Zhang),* J. Phys. Chem. Lett.2020, http://dx.doi.org/10.1021/acs.jpclett.0c02116.

28.Macromolecular Phase Transition-Driven Motility of Hollow Hydrogel Tubes. Qing Chen, Wei Huang, Qiuhua Zhao, Lidong Zhang*, ACS Applied, Polymer, Materials, 2020, https://dx.doi.org/10.1021/acsapm.0c00609.

27.In-situ swelling-driven chemical sensing actuator.Fushun Wang, Baoguo Chen, Lei Wu, Qiuhua Zhao, Lidong.    Zhang*. Cell Reports Physical Science, 2020, 1, 100011, 1-14 (Cell旗下子刊).

26.Yao Zhang, Shuaifeng Zhou, Lidong Zhang, Qiwen Yan, Lina Mao, Yiqian Wu, Wei Huang. Pre-Stretched double network polymer films based on agarose and polyacrylamide with sensitive humidity-responsive deformation, shape memory, and self-Healing properties, Macromol. Chem. Phys. 2020, 221: 1900518

2019年

25.Humidity-Driven Soft Actuator Built up Layer-by-Layer and Theoretical Insight into Its Mechanism of Energy Conversion. Huiyan Tan, Xiunan Yu, Yaqing Tu, Lidong Zhang *.J. Phys. Chem. Lett.2019, 10, 5542−5551

24.Microscopical hollow hydrogel springs, necklaces and ladders: a tubular microrobot as a potential vascular scavenger. Shumin Liang, Yaqing Tu, Qing Chen, Lidong Zhang *.Mater. Horiz.2019,6, 2135

23.Photocrosslinking Patterning of Single-Layered Polymer Actuators for Controllable Motility and Automatic Devices. Jiang Wei, Xiaxin Qiu, Lidong Zhang*.ACS Appl. Mater. Interfaces, 2019,11, 16252

22. Controllable Kinematics of Soft Polymer Actuators Induced by Interfacial PatterningHuiyan Tan, Shumin Liang, Xiunan Yu,Xiaodong Song,Wei Huang,Lidong Zhang*. J. Mater. Chem. C. 2019, 7, 5410 - 5417

21.Anti-freezing heat-resistant hollow hydrogel tubeYaqing Tu, Qing Chen, Shumin Liang, Xuechang Zhou, Wei Huang, Xinhua Huang, Lidong Zhang*.ACS Appl. Mater. Interfaces,2019,11, 18746

20.Highly-stretchable tough polymer actuator driven by acetone vaporsYihui Yuan, Jun Yuan, Ting Zhang, Huijing Han, Wei Huang, Lidong Zhang*.Macromolecular Materials and Engineering. 2019, 304, 1800501

19.Experimental Insight into Evolutionary Mechanism of Solid-to-Hollow Hydrogel. Qing Chen, Huiyan Tan, Yaqing Tu, Lidong Zhang *.Chem. Commun. 2019, 55, 11470 - 11473

18.Pre-patterning and post-oxidation-crosslinking of Fe(0) particles for a humidity-sensing actuatorXiaxin Qiu,a Shumin Liang, Xinhua Huang, Lidong Zhang *.Chem. Commun.2019, 55, 15049

17.Molecular Engineering of Supercapacitor Electrodes with Monodispersed N-Doped Carbon Nanoporous Spheres. Xinhua. Huang,* N. Wang, F. Li, X. Zhu, K. liao, V. Chan, Lidong. Zhang*. New Journal of Chemistry.2019. 43, 15892

16. Shuaifeng Zhou, Fei Cun, Yao Zhang, Lidong Zhang, Qiwen Yan, Yushi Sun,Wei Huang. Thermo-responsive aluminum-based polymer composite films with controllable deformation, J. Mater. Chem. C, 2019, 7: 7609-7617

2018年

15. Jie Chen, Hongfei Li, Hengchen Zhang, Xiaojuan Liao, Huijing Han, Lidong Zhang, Ruyi Sun and Meiran Xie. Blocking-cyclization technique for precise synthesis of cyclic polymers with regulated topology, Nat. Commun.2018, 9, 5310.

14. Yaqing Tu, Jun Yuan, Dan Lei, Huiyan Tan, Jiang Wei, Wei Huang and Lidong Zhang  *, TiO₂-Pattern-Modulated Actuation of Agarose@CNT/Agarose Bilayer Induced by Light and Humidity. J. Mater. Chem. A, 2018, 6, 8238–8243.

13. Yubing Xiong, Lidong Zhang (共一作者), Philipp Weis, Panče Naumov, and Si Wu. A Solar Actuator Based on Hydrogen-Bonded Azopolymers for Electricity Generation.J. Mater. Chem. A,2018, 6, 3361–3366.

12. Shumin Liang, Xiaxin Qiu, Jun Yuan, Wei Huang, Xuemin Du, Lidong Zhang *, Multi-Responsive Kinematics and Robotics of Surface-Patterned Polymer Film. ACS Appl. Mater. Interfaces, 2018, 10, 19123.

11. Qilong Zhao, Huanqing Cui, Juan Wang, Hongxu Chen, Yunlong Wang, Lidong Zhang*, Xuemin Du, and Min Wang, Regulation Effects of Biomimetic Hybrid Scaffolds on Vascular Endothelium Remodeling. ACS Appl. Mater. Interfaces,2018, 10, 23583-23594.

10.Jiang Wei, Fushun Wang, Wei Huang, Lidong Zhang *, Micropatterning of highly stretchable tough polymer actuators for multistage detection of acetone vapors. 2018, ACS Appl. Mater. Interfaces,2018, 10, 29161-29168.

9. Qing Chen, Shumin Liang, Xiaodong Song, Panče Naumov, Lidong Zhang *, Hollow hydrogel networks for temperature-controlled water fluidics. Chem. Comm.2018, 54, 10304--10307.

8. Chenxiao Xiong, Lidong Zhang, Meiran Xie, and Ruyi Sun. Photoregulating of Stretchability and Toughness of a Self-Healable Polymer Hydrogel, Macromol. Rapid Commun.2018, 39, 1800018.

2017年

 7. Lidong Zhang *, Panče Naumov, Xuemin Du, Zhigao Hu and Juan Wang. Vapomechanically Responsive Motion of Microchannel-Programmed Actuators. Adv. Mater.,2017, 29, 1702231.

6. Lidong Zhang *, Yihui Yuan, Xiaxin Qiu, Ting Zhang, and Qing Chen. Marangoni Effect-Driven Motion of Miniature Robots and Generation of Electricity on Water. Langmuir, 2017, 33, 12609−12615.

5.Lidong Zhang * Xiaxin Qiu, Yihui Yuan, Ting Zhang. Humidity- and Sunlight-Driven Motion of a Chemically Bonded Polymer Bilayer with Programmable Surface Patterns. ACS Appl. Mater. Interfaces, 2017, 9, 41599−41606.

2016年

4. Lidong Zhang, Israel Desta and Pance Naumov*. Synergistic action of thermoresponsive andhygroresponsive elements elicits rapid and directional response of a bilayer actuator. Chem Commun., 2016, 52, 5920-5923, 封面文章.

3. Lidong Zhang, Stanislav Chizhik,Yunze Wen and Pance Naumov*. Directed Motility of Hygroresponsive Biomimetic Actuators. Adv. Funct. Mater., 2016, 26, 1040.

2015年

2. Lidong Zhang, Haoran Liang, Jolly Jacob. Panče Naumov*. Photogated Humidity-Driven Motility. Nature Commun., 2015, 6:7429, 1-8.

1. Lidong Zhang, Panče Naumov*. Light- and Humidity-Induced Motion of Acidochromic Film. Angew. Chem. In. Ed. 2015, 54, 8642-8647, VIP文章.

学术会议报告

1) Smart Hybrid Polymer Converts Humidity, Light and Heat into Mechanical Work (邀请报告，奥地利) The 3rdEuropean Symposium of Photopolymer Science, Vienna, Austria. September 9-12, 2014。

2) Photogatinged Humidity-Driven Motility (邀请报告，阿联酋), Dubai Nanotech 2015, Dubai, United Arab Emirates. April 15, 2015。

3) Bio-Inspired Multiresponsive Polymer Composites for Energy Conversion (邀请报告，德国)

Max Planck Institute for Polymer Research Department in Mainz, Germany. April 20, 2015。

4) Smart Polymer Composites: Photogated Humidity-Driven Motility (邀请报告，中国)，International Symposium on Photopolymerization, Beijing, China. June 28-July 1, 2015。

5) Photogated Motility in Smart Actuators with Dual Response (邀请报告，美国), The 1st International Conference on Smart Materials and Structures, Las Vegas, US. June 15–17, 2015。

6) Directed Motility of Hygroresponsive Biomimetic Actuators (口头报告，阿联酋), The 8th International Conference on Materials Science and Engineering (IMS8), American University of Sharjah, United Arab Emirates. February 2 ‒ 3, 2016。

7)Fast Motility of Hygroscopic Actuator (邀请报告，新加坡), The Energy Materials Nanotechnology Meeting on Hydrogel materials, Singapore. May 9–13, 2016。

8) Fast Motility of Hygroresponsive Biomimetic Actuators (邀请报告), BIT’s 5th Annual World Congress of Advanced Materials, Chongqing, China. June 6 – 8, 2016。

9) Fast Motility of Hygroresponsive Actuators (邀请报告，韩国), The third SPIE’s International Conference on Nano-Bio Sensing, Imaging & Spectroscopy (SPIE-NBSIS 2017) Jeju, South Korea. February 22-24, 2017。

10) Biomimetic actuation of stimuli-responsive polymer composites（口头报告，厦门）, The 15th Pacific Polymer Conference Xiamen, China, December 10-14th , 2017.

11) 溶剂分子驱动智能高分子膜的连续形变运动（墙报，成都），2017年全国高分子学术论文报告会，2017年10月10-14.

12) Perpetual and Fatigueless Motion of Vapomechanically Responsive Actuators (深圳)，第一届仿生智能材料青年论坛（会议发起人及协办人），中国科学院深圳先进技术研究院，2017年7月20-21号。

13) 柔性智能高分子膜的仿生运动及其传感应用研究（口头报告，杭州），中国化学会第31届学术年会，2018年5月5-8号。

14) Stimuli-Responsive Polymer Composites with Controllable Kinematics （邀请报告，西安），第七届材料科学与工程国际会议，2018年11月1日-11月4日。

15) Shape-programmed actuation of stimuli-responsive polymer composites （口头报告，南京）Advances in Functional Materials International Conference, Nanjing, China, 2018 年8月27-30日。

16) Stimuli-responsive polymer composites（口头报告，桂林），The 7th Spring World Congress on Engineering and Technology Guilin, China, April 23-25, 2018 April 23-25。

17）柔性智能高分子膜的能量转化性能及传感应用研究（邀请报告，苏州），WILEY-苏州大学能源材料国际研讨会，2018年12月21-23号。

18) 柔性智能高分子材料基础及应用(邀请报告，武汉)，第二届仿生智能材料青年论坛，武汉, 2019年11月30号。

19) Controlled Kinematics of Smart Film Actuators (邀请报告，上海), Collaborative Conference on Materials Science and Technology (CCMST) 2019年10月 14 to 18日, Shanghai, China.

20) Surface Functionalization of Polymers for Response-controllable Soft Actuators (口头报告，新加坡)，The 16th Pacific Polymer Conference (PPC16), December 8 to 12. 2019.

21) 柔性智能高分子材料基础及应用(邀请报告，重庆), 环境与能源高分子材料学术论坛, 2019年12月13-15号。

22) Controlled actuation of stimuli-responsive polymer composites (邀请会议，哈尔滨), The 7th International Conference on Smart Materials and Nanotechnology in Engineering (SMN 2019). 2019 年 9 月 20 日－23 日.

23) “一步法”转化水凝胶薄膜到复杂多支中空微流管(口头报告，大连), 2019 年中国生物材料大会暨国际先进生物材料大会, 8月22-25号。

24) 刺激响应薄膜的多级组装及能量转化理论研究(口头报告，西安)，2019 年全国高分子学术论文报告会, 10月15-19号。

25) Hollow Hydrogel Networks for Temperature-Controlled Water Fluidics (邀请报告，西安), International Symposium for Advanced Gel Materials & Soft Matters, ISAGMSM, June 15-17, 2019, Xi An. China。

专利：

1.张利东，一种双层智能薄膜的制备及其在可控柔性器件方面的应用，

 中国专利申请号或专号：201710224224.4，申请日：2017年4月7日。

2. Il Kim, Lidong Zhang, “Hydrogel and drug delivery system using thereof”. Korean    Patent, 2012,App.No. 10-2-12-0009118.

3. Il Kim, Lidong Zhang, “Catalyst comprising hydrogel and active ingredient”. Korean  Patent, 2012,App. No. 10-2-12-0047001.

欢迎高分子化学，有机合成化学背景的学生报考本课题组的硕士，博士研究生。