陆嘉星

        中国有机电化学和工业行业联合会副理事长

        《电化学》编委‍

‍

       应用电化学

       电化学催化

       电化学合成

       本课题组主要在有机电化学、电化学催化、导电聚合物膜的制备及其催化、电极过程动力学等方面进行了一定的应用基础研究。特别是近年来，以CO₂为主要原料之一，在温和条件下进行有机碳酸酯、有机化合物电化学羧化反应、有机电化学不对称合成的研究，电化学还原CO₂合成有机小分子化合物的研究等形成了一定的特色。

主持项目:

1) 纳米分子修饰电极的组装及其在CO₂转化反应中的应用

国家自然科学基金项目（21373090） 2014.1-2017.12.

2) 过渡金属配合物电催化氢化CO₂制甲醇的研究
国家自然科学基金项目（21173085） 2012.1-2015.12.

3) CO₂参与的不对称电羧化合成手性有机羧酸化合物的研究
国家自然科学基金项目（20973065） 2010.1-2012.12.

4) 离子液体中固定CO₂进行有机碳酸酯的电化学合成及机理
国家自然科学基金项目（20573037） 2006.1-2008.12.

5) CO₂综合利用的若干关键科学问题研究（其中子项目）
上海市科委重大基础研究项目（08dj1400100） 2008.9-2011.8.

6) CO₂和CH₄的活化及碳链增长
上海市科委重点项目（05JC14070） 2005.10-2007.9.

7) 电化学合成开发

上海富臣化工有限公司 2012.1-2016.12

代表性论文：

1、Heng-Pan Yang, Sen Qin, Huan Wang^* andLu, J. X.* Organically doped palladium: a highly efficient catalyst for electroreduction of CO2 to methanol. Green Chem., 2015, 17, 5144–5148

2、Heng-Pan Yang, Ying-Na Yue, Qi-Long Sun, Qiu Feng, Huan Wang^* and Lu, J. X.* Entrapment of a chiral cobalt complex within silver: a novel heterogeneous catalyst for asymmetric carboxylation of benzyl bromides with CO2. Chem. Commun., 2015, 51, 12216—12219.

3、Heng-Pan Yang, HuanWang, Lu, J. X.* lkaloid-induced asymmetric hydrogenation on a Cu nanoparticle cathode by electrochemical conditions. Electrochem.Commun. 55 (2015) 18–21

4、Laxia Wu, Hengpan Yang, Huan Wangb andLu, J. X.*Electrosynthesis of cyclic carbonates from CO2 and epoxides on a reusable copper nanoparticle cathode. RSC Adv., 2015, 5, 23189–23192

5、Huan Wang, Li He, Guo-Jiao Sui and Lu, J. X.* Electrocatalytic reduction of PhCH2Br on a Ag–Y zeolite modified electrode. RSC Adv., 2015, 5, 42663–42665

6、Yang, H. P.; Chi, D. H.; Sun, Q. L.; Sun, W. W.; Wang, H.^*;Lu, J. X.^*, Entrapment of alkaloid within silver: from enantioselective hydrogenation to chiral recognition. Chem. Commun.2014, 50 (64), 8868-8870.

7、Xiao, Y.; Chen, B. L.; Yang, H. P.; Wang, H.^*; Lu, J. X.^*, Electrosynthesis of enantiomerically pure cyclic carbonates from CO2 and chiral epoxides. Electrochem. Commun.2014, 43 (0), 71-74.

8、Chen, B. L.; Zhu, H. W.; Xiao, Y.; Sun, Q. L.; Wang, H.^*;Lu, J. X.^*, Asymmetric electrocarboxylation of 1-phenylethyl chloride catalyzed by electrogenerated chiral [CoI(salen)]− complex. Electrochem. Commun.2014, 42 (0), 55-59.

9、Chen, B. L.; Tu, Z. Y.; Zhu, H. W.; Sun, W. W.; Wang, H.^*; Lu, J. X.^*, CO2 as a C1-organic building block: Enantioselective electrocarboxylation of aromatic ketones with CO2catalyzed by cinchona alkaloids under mild conditions. Electrochim. Acta. 2014,116 (0), 475-483.

10、Wang, H.; Xu, X. M.; Lan, Y. C.; Wang, H. M.;Lu, J. X.^*, Electrocarboxylation of haloacetophenones at silver electrode. Tetrahedron2014, 70 (6), 1140-1143.

11、Yang, H. P.; Lv, T.; Sun, W. W.; Du, Y. F.; Wang, H.^*; Lu, J. X.^*, Enantioselective hydrogenation of methyl benzoylformate on Ag electrode electrosorbed with cinchonine. RSC Adv.2014, 4 (58), 30584-30586.

12、Chi, D. H.; Yang, H. P.; Du, Y. F.; Lv, T.; Sui, G. J.; Wang, H.^*; Lu, J. X.^*, Morphology-controlled CuO nanoparticles for electroreduction of CO2 to ethanol. RSC Adv.2014, 4, 37329-37332.

13、Yangchun Lan,Chao Gai, Paul J.A. Kenis^*, Jiaxing Lu^*, Electrochemical Reduction of Carbon Dioxide on Cu/CuO Core/Shell Catalysts. ChemElectroChem. 2014, 1, 1577-1582.

14、Chen, B. L.; Xiao, Y.; Xu, X. M.; Yang, H. P.; Wang, H.^*; Lu, J. X.^*, Alkaloid induced enantioselective electroreduction of acetophenone. Electrochim. Acta2013, 107 (0), 320-326.

15、Zhang, G. R.; Ding, B. B.; Wu, L.; He, L.; Ni, B.; Lu, J. X.^*, Possible tuning fabrication of nanoplatinum particles with the conducting copolymer films and their behavior toward the electrooxidation of methanol. J. Appl. Polym. Sci.2013, 129 (3), 1593-1606.

16、Zhao, S. F.; Lu, J. X.^*; Bond, A. M.^*; Zhang, J.^*, Remarkable Sensitivity of the Electrochemical Reduction of Benzophenone to Proton Availability in Ionic Liquids. Chem. Eur. J.2012, 18 (17), 5290-5301.

17、Zhao, S. F.; Lu, J. X.^*; Bond, A. M.^*; Zhang, J.^*, Voltammetric studies in “wet” 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquid using electrodes with adhered microparticles. Electrochem. Commun.2012, 16 (1), 14-18.

18、Wu, L. X.; Wang, H.; Xiao, Y.; Tu, Z. Y.; Ding, B. B.; Lu, J. X.^*, Synthesis of dialkyl carbonates from CO2 and alcohols via electrogenerated N-heterocyclic carbenes. Electrochem. Commun.2012, 25 (0), 116-118.

19、Wang, H.; Wu, L. X.; Zhao, J. Q.; Li, R. N.; Zhang, A. J.; Kajiura, H.; Li, Y. M.; Lu, J. X^*., Synthesis of cyclic carbonates from CO2 and diols via electrogenerated cyanomethyl anion. Greenhouse Gases: Science and Technology2012, 2 (1), 59-65.

20、Wu, L. X.; Wang, H.; He, L.; Wu, L.; Zhang, A. J.; Kajiura, H.; Li, Y. M.; Lu, J. X.^*, Direct Electrosynthesis of Organic Carbonates from CO2 with Alcohols Under Mild Condition. Int. J. Electrochem. Sci.2012, 7 (6), 5616-5625.

21、Zhao, S. F.; Wu, L. X.; Wang, H.; Lu, J. X.^*; Bond, A. M.^*; Zhang, J.^*, A unique proton coupled electron transfer pathway for electrochemical reduction of acetophenone in the ionic liquid [BMIM][BF4] under a carbon dioxide atmosphere. Green Chem.2011, 13 (12), 3461-3468.

22、Wang, H.; Zhang, K.; Chen, B. L.; Li, R. N.; Zhao, J. Q.; Lu, J. X.^*, Study on Electrocarboxylation of [(4-Methoxy-Benzylidene)-Amino] - Acetic Acid Ester. Int. J. Electrochem. Sci.2011, 6 (5), 1720-1729.

23、Wang, H.; Wu, L. X.; Lan, Y. C.; Zhao, J. Q.; Lu, J. X.^*, Electrosynthesis of Cyclic Carbonates From CO2 and Diols in Ionic Liquids Under Mild Conditions. Int. J. Electrochem. Sci.2011, 6 (9), 4218-4227.

24、Zhang, K.; Xiao, Y. J.; Lan, Y. C.; Zhu, M. X.; Wang, H.^*; Lu, J. X.^*, Electrochemical reduction of aliphatic conjugated dienes in the presence of carbon dioxide. Electrochem. Commun.2010, 12 (12), 1698-1702.

25、Zhang, G. R.; Zhang, A. J.; Liu, X. L.; Zhao, S. F.; Zhang, J. B.; Lu, J. X.^*, Investigation of the Electropolymerization of o-Toluldine and p-Phenylenediamine and Their Electrocopolymerization by In Situ Ultraviolet-Visible Spectro electrochemistry. J. Appl. Polym. Sci.2010, 115 (5), 2635-2647.

26、Wang, H.; Zhao, C.; Bhatt, A. I.; MacFarlane, D. R.; Lu, J. X.^*; Bond, A. M.^*, Electrochemical Study of Dialcarb "Distillable" Room-Temperature Ionic Liquids. ChemPhysChem.2009, 10 (2), 455-461.

27、Zhang, K.; Wang, H.; Zhao, S. F.; Niu, D. F.; Lu, J. X.^*, Asymmetric electrochemical carboxylation of prochiral acetophenone: An efficient route to optically active atrolactic acid via selective fixation of carbon dioxide. J. Electroanal. Chem.2009, 630 (1-2), 35-41.

28、Zhang, A. J.; Chen, J.; Niu, D. F.; Wallace, G. G.; Lu, J. X.^*, Electrochemical polymerization of pyrrole in BMIMPF6 ionic liquid and its electrochemical response to dopamine in the presence of ascorbic acid. Synth. Met.2009, 159 (15-16), 1542-1545.

29、Zhang, L.; Niu, D. F.; Zhang, K.; Zhang, G. R.; Luo, Y. W.; Lu, J. X.^*, Electrochemical activation of CO2 in ionic liquid ( BMIMBF4): synthesis of organic carbonates under mild conditions. Green Chem.2008, 10 (2), 202-206.

30、Niu, D. F.; Zhang, A. J.; Xue, T.; Zhang, J. B.; Zhao, S. F.; Lu, J. X.^*, Electrocatalytic dimerisation of benzyl bromides and phenyl bromide at silver cathode in ionic liouid BMIMBF4. Electrochem. Commun.2008, 10 (10), 1498-1501.

31、Wang, H.; Zhang, K.; Liu, Y. Z.; Lin, M. Y.; Lu, J. X.^*, Electrochemical carboxylation of cinnamate esters in MeCN. Tetrahedron2008, 64 (2), 314-318.

32、Niu, D. F.; Xiao, L. P.; Zhang, A. J.; Zhang, G. R.; Tan, Q. Y.; Lu, J. X.^*, Electrocatalytic carboxylation of aliphatic halides at silver cathode in acetonitrile. Tetrahedron2008, 64 (46), 10517-10520.

33、Wang, H.; Lin, M. Y.; Zhang, K.; Li, S. J.; Lu, J. X.^*, Electrochemical reduction of cinnamonitrile in the presence of carbon dioxide: Synthesis of cyano- and phenyl-substituted propionic acids. Aust. J. Chem.2008, 61 (7), 526-530.