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董开武

化学与分子工程学院教授

个人资料

  • 部门: 化学与分子工程学院
  • 性别:
  • 专业技术职务: 教授、课题组长
  • 毕业院校: 中科院上海有机所
  • 学位: 博士
  • 学历:
  • 联系电话: 021-54340096
  • 电子邮箱: kwdong@chem.ecnu.edu.cn
  • 办公地址: 闵行校区化学楼537
  • 通讯地址: 上海市闵行区东川路500号,华东师范大学化学楼537
  • 邮编:
  • 传真:

教育经历


2017.08-2017.09 访问研究人员,德国康斯坦茨大学材料化学系(合作导师:Stefan Mecking教授)


2014.06-2018.03 博士后,德国莱布尼兹催化研究所 (合作导师: Matthias Beller教授)


2013.07-2014.05 研究助理,中国科学院上海有机化学研究所


2008.09-2013.07 博士,中国科学院上海有机化学研究所 (导师: 丁奎岭院士)


2004.09-2008.07 学士,华东师范大学(指导教师:吴海虹教授)


工作经历

2018.03-至今  教授,华东师范大学



个人简介

2018.03-至今  教授,华东师范大学

2017.08-2017.09 访问研究人员,德国康斯坦茨大学材料化学系(合作导师:Stefan Mecking教授)

2014.06-2018.03 博士后,德国莱布尼兹催化研究所 (合作导师: Matthias Beller教授)

2013.07-2014.05 研究助理,中国科学院上海有机化学研究所

2008.09-2013.07 博士,中国科学院上海有机化学研究所 (导师: 丁奎岭院士)

2004.09-2008.07 本科,华东师范大学(指导教师:吴海虹教授)

社会兼职

研究领域

不饱和C1和C4的转化利用

连续微通道反应



招生与培养

开授课程

《高等有机化学》

《有机化学实验》


科研项目

1. 海外高层次青年人才计划(2018-2021,负责人)

2. 科技部重点研发计划,离子液体强化CO2绿色转化新过程 (2020YFA0710201,2020-2025, 课题一负责人)

3. 上海市自然科学基金原创探索项目,电化学促进以CO2为C1源的C-H键羰化反应研究 (20ZR1471400,2020-2023,负责人)

4. 上海市“科技创新行动计划”启明星项目,烯烃固定CO2的催化研究(21QA1402800,2021-2024,负责人)

5. 上海市分子智造前沿科学研究基地 (2021-2026,参与)

学术成果

23. Palladium-Catalyzed Asymmetric Hydroesterification of α-Aryl Acrylic Acids to Chiral Substituted Succinates, Xiaolei Ji, Chaoren Shen, Xinxin Tian, and Kaiwu Dong*, Organic Letters, 2021, DOI:10.1021/acs.orglett.1c03361. 

22. Improving the performance of palladium-catalysed telomerization of 1,3-butadiene by metallocene-based phosphine ligand, Hongru Zhang, Chaoren Shen,* Zhengshuai Xu, Xinxin Tian, Kaiwu Dong*, Molecular Ctalysis, 2021, DOI: 10.1016/j.mcat.2021.111883 

21. Asymmetric Alkoxy- and Hydroxy-Carbonylations of Functionalized Alkenes Assisted by β-Carbonyl Groups, Xinyi Ren, Zhen Wang, Chaoren Shen, Xinxin Tian, Lin Tang, Xiaolei Ji, Kaiwu Dong*, Angewandte Chemie International Edition, 2021DOI: 10.1002/anie.202105977 

20. Enantioselective Hydroesterificative Cyclization of 1,6-Enynes to Chiral γ-Lactams Bearing a Quaternary Carbon Stereocenter, Xinyi Ren, Lin Tang, Chaoren Shen, Huimin Li, Peng Wang, Kaiwu Dong*, Organic Letters, 2021, DOI: 10.1021/acs.orglett.1c00952 (Highlighted by Synfacts) 

19. Access to α-Cyano Carbonyls Bearing a Quaternary Carbon Center by Reductive Cyanation, Xinyi Ren, Chaoren Shen, Guangzhu Wang, Zhanglin Shi, Xinxin Tian, Kaiwu Dong*, Organic Letters, 2021DOI: 10.1021/acs.orglett.1c00465 

18. Constructing chiral aza-quaternary carbon centers by enantioselective carbonylative Heck reaction of o-iodoanilines with allenes, Zhengshuai Xu, Chaoren Shen, Hongru Zhang, Peng Wang, Kaiwu Dong*, Organic Chemistry Frontiers, 2020, DOI: 10.1039/d0qo01486a 

17. Synthesis of Enantioenriched α,α-Difluoro-β-arylbutanoic Esters by Pd-Catalyzed Asymmetric Hydrogenation, Sitian Feng,Yitian Tang,Chenjue Yang,Chaoren Shen,Kaiwu Dong*, Organic Letters2020 , DOI: 10.1021/acs.orglett.0c02700 

16. Efficient Synthesis of γLactones by CobaltCatalyzed Carbonylative Ring Expansion of Oxetanes under Syngas Atmosphere, Yitian Tang, Chaoren Shen, Qiyi Yao, Xinxin Tian, Bo Wang, Kaiwu Dong*, ChemCatChem2020DOI: 10.1002/cctc.202001294

15. Nickel-catalyzed regio- and diastereoselective hydroarylative and hydroalkenylative cyclization of 1,6-dienes, Zhengshuai Xu,Yitian Tang,Chaoren Shen,Hongru Zhang,Yuxin Gan,Xiaolei Ji,Xinxin Tian, Kaiwu Dong*, Chemical Communications2020DOI: 10.1039/c9cc09450d

14.Recent progress in transition-metal-catalyzed hydrocyanation of nonpolar alkenes and alkynes, Hongru Zhang,Xin Su,Kaiwu Dong*, Organic & Biomolecular Chemistry, 2019DOI: 10.1039/c9ob02374g

 

第一作者:

13. K. Dong, R. Sang, Z. Wei, J. Liu, R. Dühren, A. Spannenberg, H. Jiao, H. Neumann, R. Jackstell, R. Franke, M. Beller*, Cooperative catalytic methoxycarbonylation of alkenes: uncovering the role of palladium complexes with hemilabile ligands. Chem. Sci. 2018, 9, 2510-2516.

12. K. Dong, R. Razzaq, Y. Hu, K. Ding,* Homogeneous Reduction of Carbon Dioxide with Hydrogen. Top. Curr. Chem. 2017, 375, 23-48.

11. K. Dong, X.-F. Wu,* Carbonylations with CO2 as the CO Source and Reactivity Modifier. Angew. Chem. Int. Ed. 2017, 56,5399-5401.

10. K. Dong,+ R. Sang,+ J. Liu, R. Razzaq, R. Franke, R. Jackstell, M. Beller, Palladium-Catalyzed Carbonylation of sec- and tert-Alcohols. Angew. Chem. Int. Ed. 2017, 56,6203-6207.

9. K. Dong, R. Sang, X. Fang, R. Franke, A. Spannenberg, H. Neumann, R. Jackstell, M. Beller,* Efficient Palladium-catalyzed Alkoxycarbonylation of Bulk Industrial Olefins using Ferrocenyl Phosphines. Angew. Chem. Int. Ed. 2017, 56, 5267-5271.

8. K. Dong,+ X. Fang,+ S. Gülak, R. Franke, A. Spannenberg, H. Neumann, R. Jackstell, M. Beller,* Highly active and efficient catalysts for alkoxycarbonylation of alkenes. NatCommun20178, 14117-14123.

7. K. Dong, S. Elangovan, R. Sang, A. Spannenberg, R. Jackstell, K. Junge, Y. Li,* M. Beller,* Selective catalytic two-step process for ethylene glycol from carbon monoxide. Nat. Commun. 20167, 12075-12081.

6. K. Dong,+ R. Sang,+ J.-F. Soule, C. Bruneau, R. Franke, R. Jackstell, M. Beller,* Efficient Domino Hydroformylation/Benzoin Condensation: Highly Selective Synthesis of α-Hydroxy Ketones. Chem. Eur. J. 201521, 18033-18037.

5. K. Dong, X. Fang, R. Jackstell, G. Laurenczy, Y. Li,* M. Beller,* Rh(I)-Catalyzed Hydroamidation of Olefins via Selective Activation of N–H Bonds in Aliphatic Amines. J. Am. Chem. Soc. 2015137, 6053-605

4. K. Dong, X. Fang, R. Jackstell, M. Beller,* A novel rhodium-catalyzed domino-hydroformylation-reaction for the synthesis of sulphonamides. Chem. Commun. 201551, 5059-5062.

3. K. Dong, Y. Li, Z. Wang, K. Ding,* Asymmetric Hydrogenation of α-Arylacrylic and β-Arylbut-3-enoic Acids Catalyzed by a Rh(I) Complex of a Monodentate Secondary Phosphine Oxide Ligand. Org. Chem. Front20141, 155-160.

2. K. Dong, Y. Li, Z. Wang, K. Ding,* Catalytic Asymmetric Hydrogenation of α-CF3- or β-CF3-Substituted Acrylic Acids using Rhodium(I) Complexes with a Combination of Chiral and Achiral Ligands. Angew. Chem. Int. Ed201352, 14191-14195.

1. K. Dong, Z. Wang, K. Ding,* Rh(I)-Catalyzed Enantioselective Hydrogenation of α-Substituted Ethenylphosphonic Acids. J. Am. Chem. Soc.2012134, 12474-12477.


荣誉及奖励

1. 2018年,海外高层次青年人才计划

2. 2021年,上海市“科技创新行动计划”启明星项目